基于慕课堂数据的学生学习行为分析

本文结合慕课堂线上学习数据与线下考试成绩,研究学生在线学习的行为表现与学习效果之间的关联性,所获得的信息能够体现出不同学生群体的特点以及不同学习维度的作用,从而提醒教师适时调整教学策略,持续改进,有助于教师改进教学方法,提高教学质量.     

Coupled-line-based millimeter-wave CMOS spiral power dividers with tapered TLs

Analog Integrated Circuits and Signal Processing - We propose a power divider comprising of two parallel λ/4 coupled lines with a shared input signal line. An isolation resistor R is included...     

海河平原区地下水累计可恢复超采量评价

地下水累计可恢复超采量评价对于地下水超采态势评判和超采综合治理实施都具有重要意义。本文以海河平原区为研究对象，提出超采量评价方法，旨在客观准确评价地下水累计可恢复超采量。针对浅层地下水超采量，提出生态临界水位作为传统“水位动态法”评价浅层地下水超采量的临界水位，据此得到研究区1959-2019年累计浅层超采量为869亿m³；针对深层地下水超采量，提出“不可恢复超采量”评价指标，采用地面沉降体积法评价深层地下水超采量，根据地面沉降体积计算深层承压含水层系统压密释水量体积，据此估算1970-2019年深层累计超采量为756亿m³；通过建立的一维非线性压密释水数值模型，模拟了深层承压含水层系统压密释水过程，计算得到非弹性压密释水量，评估研究区累计不可恢复超采量为558亿m³。因此本文认为，自1960年代以来，海河平原区地下水浅层和深层累计超采量1625亿m³，其中可恢复的超采量仅为1067亿m³。该研究结果可为未来地下水回补水量和南水北调规划调水量的确定提供参考。     

Sustainable phenolic thermosets coatings derived from urushiol

The over-exploitation of finite fossil resources and/or the increased environmental and sustainable awareness inspire scientists and technologists to search for inexpensive alternatives from renewable chemicals. Phenol formaldehyde (PF) resins, the oldest type of synthetic polymers with good mechanical properties and heat resistance, are widely used in the production of coatings, laminates, molding compositions, and glues. Here, biobased urushiol-derived PF resins were synthesized from the alkali-catalyzed reaction between urushiol and formaldehyde. The chemical compositions and molecular structures of resole resins were characterized by carbon-13 nuclear magnetic resonance and Fourier transform infrared spectroscopy, and their curing behaviors were studied by differential scanning calorimetry. The as-prepared urushiol-derived resole resins had methylol (Ph−CH₂OH), ortho- and para-hemiformal groups (Ph−CH₂OCH₂OH), and the para−para/ortho−para/ortho−ortho links of methylene groups (Ph−CH₂−Ph), whereas the resole resins had low curing temperatures at about 100–113°C. Additionally, given the long side alkyl group moiety on the aromatic rings of urushiol, the films of cured urushiol-derived resole resins had low glass transition temperatures of 132 ± 2°C. Furthermore, the as-prepared urushiol-derived coatings exhibited excellent physical and mechanical properties.     

Reversal of the Inflammatory Responses in Fabry Patient iPSC-Derived Cardiovascular Endothelial Cells by CRISPR/Cas9-Corrected Mutation

The late-onset type of Fabry disease (FD) with GLA IVS4 + 919G > A mutation has been shown to lead to cardiovascular dysfunctions. In order to eliminate variations in other aspects of the genetic background, we established the isogenic control of induced pluripotent stem cells (iPSCs) for the identification of the pathogenetic factors for FD phenotypes through CRISPR/Cas9 genomic editing. We adopted droplet digital PCR (ddPCR) to efficiently capture mutational events, thus enabling isolation of the corrected FD from FD-iPSCs. Both of these exhibited the characteristics of pluripotency and phenotypic plasticity, and they can be differentiated into endothelial cells (ECs). We demonstrated the phenotypic abnormalities in FD iPSC-derived ECs (FD-ECs), including intracellular Gb3 accumulation, autophagic flux impairment, and reactive oxygen species (ROS) production, and these abnormalities were rescued in isogenic control iPSC-derived ECs (corrected FD-ECs). Microarray profiling revealed that corrected FD-derived endothelial cells reversed the enrichment of genes in the pro-inflammatory pathway and validated the downregulation of NF-κB and the MAPK signaling pathway. Our findings highlighted the critical role of ECs in FD-associated vascular dysfunctions by establishing a reliable isogenic control and providing information on potential cellular targets to reduce the morbidity and mortality of FD patients with vascular complications.     

Differences in indentation and wear behaviors between the two sides of thermally tempered soda lime silica glass

Thermal tempering is an industrial process widely used to make soda lime silica (SLS) glass panels stronger and tougher. During the tempering process, the upper and bottom sides of the glass may experience different cooling rates, and thus, their properties could be different. This study characterized changes in surface composition and subsurface glass network structures as well as indentation and wear resistance properties of the air- and tin-sides of 6-mm-thick SLS window panels faced toward the upper and sliding roller sides during thermal tempering. The results showed that although the chemical and structural differences detected with X-ray photoelectron spectroscopy and specular reflection infrared spectroscopy are subtle, there are large differences in nanoindentation behaviors and mechanochemical wear properties of the SLS glass surface. The findings of this study provide further insights into the performance difference between the air- and tin-sides of the SLS glass panel treated with thermal tempering.     

Photomemory and Pulse Monitoring Featured Solution-Processed Near-Infrared Graphene/Organic Phototransistor with Detectivity of 2.4 × 1013 Jones

Emerging graphene/organic phototransistors are eye-catching technologies owing to their unique merits including easy/low-cost fabrication, temperature independent, and achieving various functions. However, their development in the near-infrared (NIR) region is experiencing a bottleneck of inferior sensitivity due to low exciton dissociation efficiency and inefficient charge extraction rate. Here, a novel-design solution-processed graphene/organic NIR phototransistor is reported, that is, creatively introducing electron extraction layer of ZnO on graphene channel and employing organic ternary bulk heterojunction as photosensitive layer, successfully breaking that bottleneck. The phototransistor exhibits a high responsivity of 6.1 × 10⁶ A W⁻¹, a superior detectivity of 2.4 × 10¹³ Jones, and a remarkable minimum detection power of 1.75 nW cm⁻² under 850 nm radiation. Considering its excellent NIR detection performance, a noncontact transmission-type pulse monitoring is carried out with no external circuit support, from which human pulse signal and heart rate can be displayed in real time. The phototransistor, interestingly, can be switched into a photomemory function with a retention time of 1000 s in the atmosphere through a gate voltage of −20 V. The design takes the characteristics of graphene/organic phototransistors to a higher level, beyond the limit of sensitivity, and opens up a novel approach for developing multifunction devices.     

葫芦容器生态包装设计探析

目的 研究葫芦容器作为生态材料在包装设计中的运用.方法 从葫芦容器的渊源和表现形式两个方面探究,明晰了葫芦作为容器就具备存放盛装、便利实用的包装功能.分析和探讨葫芦作为包装容器的优势,体现在葫芦材质、葫芦造型、葫芦工艺方面,归纳总结出葫芦是现成的生态包装容器,材质安全无害易降解,自然培育无环境破坏压力,符合绿色环保要求.结论 结合实践设计提出葫芦容器的生态化、形态化、功能性的设计延伸再利用,以及葫芦容器的产业化生产的可行性探讨,以期使葫芦容器得到传承与推广.     

广播电视技术与互联网技术融合的优势

随着互联网时代的发展,互联网技术逐渐延伸覆盖至各个领域.作为人们生产生活不可或缺的元素,广播电视与互联网技术不断融合,能优化传统业态,带给人们优质的服务体验.当前,如何在全新的发展形势下打破广播电视在传播信息、传播形式、传播媒介等方面的局限性,适应人们碎片化、快节奏生活的信息需求,积极融合互联网技术,成为媒体从业者亟待解决的课题.     

Occupational exposure and health risks of volatile organic compounds of hotel housekeepers: Field measurements of exposure and health risks

Hotel housekeepers represent a large, low-income, predominantly minority, and high-risk workforce. Little is known about their exposure to chemicals, including volatile organic compounds (VOCs). This study evaluates VOC exposures of housekeepers, sources and factors affecting VOC levels, and provides preliminary estimates of VOC-related health risks. We utilized indoor and personal sampling at two hotels, assessed ventilation, and characterized the VOC composition of cleaning agents. Personal sampling of hotel staff showed a total target VOC concentration of 57 ± 36 µg/m³ (mean ± SD), about twice that of indoor samples. VOCs of greatest health significance included chloroform and formaldehyde. Several workers had exposure to alkanes that could cause non-cancer effects. VOC levels were negatively correlated with estimated air change rates. The composition and concentrations of the tested products and air samples helped identify possible emission sources, which included building sources (for formaldehyde), disinfection by-products in the laundry room, and cleaning products. VOC levels and the derived health risks in this study were at the lower range found in the US buildings. The excess lifetime cancer risk (average of 4.1 × 10⁻⁵) still indicates a need to lower exposure by reducing or removing toxic constituents, especially formaldehyde, or by increasing ventilation rates.